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Updated: Sep 19, 2025

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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Understanding Small Molecule Activation Promoted by Heavier Benzene 1,4-diides: Interplay Between Diradical Character

Daniel González-Pinardo1, Rajendra S Ghadwal2, Israel Fernandez1

  • 1Departmento de Química Orgánica and Centro de Innovación en Química Avanzada (ORFEO-CINQA), Facultad de Ciencias Químicas, Universidad Complutense de Madrid, Madrid, 28040, Spain.

Chemistry (Weinheim an Der Bergstrasse, Germany)
|June 16, 2025
PubMed
Summary

Reactivity and diradical character in heavier Group 14 benzene-1,4-diides increase down the group. This study quantifies these properties and their impact on chemical reactions.

Keywords:
DFT/ab‐initio calculationsaromaticitybond activationdiradicalsmain‐group

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