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Related Concept Videos

Colloids03:22

Colloids

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Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles that are visible to the naked eye or can be seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. On the other hand, a solution is a homogeneous mixture in which no settling occurs and in which the dissolved...
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Optimizing Lubricant Deposition on Hair-like Substrates Using Cationic Polymer/Anionic Surfactant Complexes.

Nikol K Dimitrova1, Mihail T Georgiev1,2, Svetoslav E Anachkov1

  • 1Department of Chemical and Pharmaceutical Engineering, Faculty of Chemistry and Pharmacy, Sofia University St. Kliment Ohridski, 1 James Bourchier Blvd., Sofia 1164, Bulgaria.

Langmuir : the ACS Journal of Surfaces and Colloids
|June 30, 2025
PubMed
Summary

Cationic polymers and anionic surfactants in shampoos form complexes that deposit oils on hair. Cat-Guar/SLES-1EO complexes show superior deposition compared to cat-HEC/SLES-1EO, optimizing shampoo performance.

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Area of Science:

  • Colloid and Surface Science
  • Materials Science
  • Formulation Science

Background:

  • Oppositely charged polymer-surfactant mixtures have unique properties and applications.
  • Cationic polymers with anionic surfactants are used for oil deposition on hair and skin.
  • Complex formulations of these mixtures are less understood than simple systems.

Purpose of the Study:

  • To investigate polymer-surfactant complexes (PSCs) of cationic polysaccharides (cat-Guars, cat-HECs) and sodium laureth-1 sulfate (SLES-1EO) in shampoo.
  • To analyze PSCs' phase behavior, interfacial adsorption, bubble stickiness, and hair deposition.
  • To elucidate the deposition mechanism for optimizing polymer performance in formulations.

Main Methods:

  • Phase behavior analysis
  • Zeta potential measurements
  • Foam film experiments
  • Imaging ellipsometry

Main Results:

  • Cat-Guar/SLES-1EO complexes showed wider precipitation regions and higher silicone oil/water interface adsorption than cat-HEC/SLES-1EO.
  • Only cat-Guar/SLES-1EO complexes formed sticky PSCs that bridged air bubbles and silicone drops to hair.
  • Cat-Guars deposited thick, inhomogeneous layers of PSCs and silicone on hair-like substrates; cat-HECs deposited little to nothing.

Conclusions:

  • Cat-Guar/SLES-1EO complexes are more effective in deposition applications within shampoo formulations.
  • The study elucidates the deposition mechanism, offering strategies for optimizing polymer performance.
  • Comprehensive experimental protocols can guide the development of advanced personal care products.