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Updated: Sep 15, 2025
Synthesis of Bimetallic Pt/Sn-based Nanoparticles in Ionic Liquids
Published on: August 23, 2018
Synthesis and electronic structure elucidation of bioinspired heterobimetallic nickel complexes
Claire R Patterson1, Paul H Oyala2, Joshua A Buss1
1Willard Henry Dow Laboratory, Department of Chemistry, University of Michigan, Ann Arbor, MI 48109, USA. jbuss@umich.edu.
None:
Despite relevance to metalloenzyme active-sites, the selective synthesis of heterobimetallic compounds featuring unbiased, biologically relevant coordination environments remains a challenge. Herein, we disclose a stepwise synthetic strategy, leveraging kinetic stabilization by an alkali metal cation, as a means of accessing spectroscopically pure M(II)/Ni(II) (M = Co & Cu) bimetallics. Electron paramagnetic resonance spectroscopy, variable temperature magnetometry, and DFT calculations support perturbation of the electronic structure as a function of the heterometal within these closely related complexes.
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