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Pork-Derived Porous Carbon for Supercapacitors: Achieving "Near-Zero-Loss" and Ultralong Cycle Life
Haoyang Peng1,2, Huihua Li2, Yulei Liu3
1State Key Laboratory of Chemical Resource Engineering, Beijing Key Laboratory of Electrochemical Process and Technology for Materials, Beijing University of Chemical Technology, Beijing 100029, P. R. China.
None:
While biomass-derived carbon materials have been extensively explored in the field of energy storage, research focusing on animal protein as a precursor remains relatively scarce, and its potential value is yet to be fully exploited. In this study, oxygen-rich protein-based biomass porous carbons were prepared using pork as the raw material and phosphate distarch as the additive via a strategy involving compositing, subsequent carbonization, and KOH activation. Among these carbons, sample APE-2 possessed a high oxygen content of 9.81%, a hierarchical micromesoporous structure dominated by micropores, specific surface area (SSA) per unit amount of 1599 m2 g-1, and pore volume at 0.692 cm3 g-1. Under a three-electrode cell where 6 M KOH functions as the electrolyte, it demonstrated an excellent reversible specific capacitance of 565 F g-1 under 1 A g-1 as well as outstanding rate capability, maintaining a specific capacitance of 474 F g-1 even at 35 A g-1. When utilized as electrode materials to assemble symmetric supercapacitors (SCs) using 6 M KOH, it achieved a prominent reversible specific capacitive performance at 250 F g-1 under 0.5 A g-1 as well as remained at 143 F g-1 under 20 A g-1. It also exhibits an ultrastable cycling behavior with nearly "zero decay" as evidenced by a capacitance retention of 99.7% after 20,000 cycles.
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