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Updated: Jan 13, 2026

Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production
Published on: December 6, 2021
Emerging Applications of Thiol-Based Catalysts in Hydrogen Atom Transfer Reactions: A Comprehensive Review
Hao Yang1, Yanyan Liao1, Hao Guo2
1School of Chemistry and Molecular Engineering, East China Normal University, 3663 North Zhongshan Road, Shanghai 200062, China.
Abstract:
Hydrogen atom transfer (HAT) is a fundamental class of radical transformations that enables the direct generation of open-shell radical intermediates from R-H bonds (R = C, N, etc.), offering unique opportunities for green and sustainable synthesis. Significant progress has been made not only in identifying diverse molecular scaffolds capable of mediating HAT but also in developing synthetic methodologies to achieve precise stereocontrol in these processes. In this context, this review highlights recent advances in the use of sugar-derived compounds, cysteine-containing peptides, and chiral/achiral thiols/thiophenols as catalysts for stereoselective HAT, emphasizing their potential to expand the synthetic utility of HAT in organic transformations.
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