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Comparison Between Emerging and Conventional Methods for Edible Oils Bleaching.

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Summary

Industrial oil bleaching with acid-activated clay causes significant drawbacks. Novel methods like ultrasound and microwave-assisted bleaching offer cost-effective, efficient alternatives for oil purification.

Keywords:
cost–benefitfriendly environmentnovel bleaching methodreduced clay consumption

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Area of Science:

  • Food Science
  • Chemical Engineering
  • Materials Science

Background:

  • Industrial oil bleaching (IB) traditionally uses acid-activated clay, leading to issues like long filtration times, oil loss, and waste generation.
  • High temperatures and extended periods in IB contribute to triacylglycerol degradation, increased oil acidity, and undesirable byproduct formation.

Purpose of the Study:

  • To investigate and compare the effectiveness of traditional industrial bleaching methods with emerging technologies for oil purification.
  • To highlight the drawbacks of current industrial oil bleaching practices and explore innovative alternatives.

Main Methods:

  • Review of adsorption isotherms (Freundlich, Langmuir), kinetic studies (pseudo-first-order, pseudo-second-order), and thermodynamic analyses.
  • Comparison of conventional acid-activated clay bleaching with emerging methods such as ultrasound (US), microwave (MW), high-voltage electric field (HVEF), and membrane (MB) assisted bleaching.

Main Results:

  • Acid-activated clay bleaching results in prolonged filtration, oil loss, and environmental concerns.
  • Emerging technologies show potential to enhance sorption capacity, reduce adsorbent quantity, and lower processing time and temperature.
  • Adsorption processes are characterized by heterogeneous multilayer adsorption, with kinetics often following pseudo-first or pseudo-second order models.

Conclusions:

  • Novel bleaching technologies offer promising, cost-effective alternatives to traditional acid-activated clay methods.
  • These advanced techniques can mitigate the environmental impact and operational inefficiencies associated with conventional oil bleaching.
  • The thermodynamic analysis indicates that the bleaching processes are endothermic and spontaneous, driven by entropy gains.