The Impact of Aggressive Conditions on the Mechanical and Rheological Properties of Components Produced Using
Iwona Michalska-Pożoga1, Katarzyna Bryll2, Radosław Patyk1
1Faculty of Mechanical and Energy Engineering, Koszalin University of Technology, ul. Raclawicka 15-17, 75-620 Koszalin, Poland.
Materials (Basel, Switzerland)
|November 13, 2025
Summary
Marine environments degrade 3D-printed biodegradable polymers. Recycled polylactide (rPLA) and wood-polymer composites (WPC) showed significant decreases in molecular weight and mechanical properties after nine months, impacting their suitability for maritime use.
Area of Science:
- Materials Science
- Polymer Science
- Environmental Science
Background:
- Aging of polymeric materials in aggressive environments is a critical research area.
- Developing durable polymers is essential for sustainable economies and waste reduction.
- Additive manufacturing offers potential for customized polymer components, but their environmental durability requires investigation.
Purpose of the Study:
- To assess and quantify degradation mechanisms of additively manufactured polymers in marine environments.
- To analyze the impact of seawater corrosion on mechanical and rheological properties.
- To evaluate the performance of recycled polylactide (rPLA) and wood-polymer composites (WPC) under marine exposure.
Main Methods:
- Fused Deposition Modeling (FDM) used for material fabrication.
- Exposure of rPLA and WPC samples to simulated marine environments for nine months.
- Quantitative analysis of changes in molecular weight, tensile strength, and elastic modulus.
Main Results:
- rPLA showed a 16% decrease in molecular weight, 37% reduction in tensile strength, and 24% decrease in elastic modulus.
- WPC exhibited a 20% decrease in molecular weight, 30% reduction in tensile strength, and 51% drop in elastic modulus.
- Both materials demonstrated significant degradation, indicating susceptibility to marine conditions.
Conclusions:
- Additively manufactured biodegradable polymers, including rPLA and WPC, are susceptible to degradation in aggressive marine environments.
- Quantitative data highlights the need for material optimization for long-term performance in maritime and coastal applications.
- Further research is necessary to enhance the durability and extend the service life of these polymers in marine settings.


