Construction of PVDF/BTO Fibers with High Piezoelectricity for Self-Powered Flexible Pressure Sensing

As demanded by the rapid development of wearable electronics, flexible pressure sensors have attracted more and more attention worldwide. However, the performance of pressure sensors based on the piezoelectric effect has not been qualified for practical application. In this work, we designed and prepared PVDF/BTO fibers by an electrospinning approach and constructed pressure sensors for various human motion detection purposes. The performance is dramatically enhanced due to the high piezoelectric coefficient of BTO nanoparticles and the utilization of PVDF matrix with a high β content. The optimized pressure sensor presents a high power density of 27.5 nW cm^-2 at 10 N load stress and remains stable even after 3000 cycles. For human action application, the maximum output voltage is up to 20 V. The optimum β content of the PVDF matrix is up to 72.9%, which in turn contributes to the high energy-harvesting capability of the designed composites. The prepared PVDF/BTO composites show benign capability for sensing various human actions. This work shapes a new strategy for high-performance pressure sensors based on piezoelectric composites.