C(sp3)-H halogenation using first-row transition metal catalysts under homogeneous conditions
Monika1, Jaipriya Khatri1, Kritika Dogra1
1Department of Chemistry, School of Natural Sciences, Shiv Nadar Institution of Eminence Deemed to be University, Delhi NCR, Gautam Buddha Nagar, Dadri, UP-201314, India. basabbijayi@gmail.com.
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The direct functionalization of unactivated C-H bonds has emerged as a promising strategy to achieve step-economical, atom-efficient, and environmentally benign chemical processes. In this context, ongoing research is focused on the design and development of biomimetic homogeneous catalysts based on first-row transition metals for C(sp3)-H halogenation under mild conditions. In essence, this review highlights key advances in catalyst design based on first-row transition metals, showcasing their growing utility in the development of new synthetic methods.
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