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Field electron emission properties of bulk diamond/expanded graphite composite cathode.
Qianyu Ji1,2,3, Yihui Zhang1,2, Jiacheng Zhang1
1School of Mechanical Engineering, Xi'an Jiaotong University, Xi'an, Shaanxi 710049, P.R. China.
Iscience
|December 25, 2025
Summary
Diamond-expanded graphite composite cathodes were created for improved field-emitting materials. A 20% content of 0.5 μm diamond particles yielded the best electron emission activity.
Area of Science:
- Materials Science
- Nanotechnology
- Surface Science
Background:
- Diamond has negative electron affinity and high thermal conductivity, but high surface resistivity limits cold cathode applications.
- Expanded graphite offers high electrical conductivity and cost-effectiveness, making it a suitable complementary material.
- Hybrid structures combining diamond and expanded graphite are desirable for synergistic field-emitting properties.
Purpose of the Study:
- To prepare diamond-expanded graphite bulk composite cathodes.
- To investigate the electron emission properties of these hybrid materials.
- To optimize the composition for enhanced field emission.
Main Methods:
- Cold pressing method was employed for synthesizing the composite cathodes.
- Characterization of electron emission activity, including turn-on field, threshold field, and current density.
- Evaluation of field enhancement factor.
Main Results:
- The composite cathode with 20% diamond content (0.5 μm particle size) showed optimal electron emission.
- Achieved turn-on field strength of 1.61 V/μm (at 1 mA/cm²) and threshold field strength of 2.11 V/μm (at 10 mA/cm²).
- Maximum current density reached 911.24 mA/cm² at 3.77 V/μm, with a field enhancement factor of 4490.
Conclusions:
- Diamond-expanded graphite composites are effective for field-emitting applications.
- Optimized composition significantly enhances electron emission performance.
- The developed material shows promise for advanced cold cathode technologies.

