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Updated: Jan 28, 2026

Residue-Free Fabrication of van der Waals Heterostructures of Two-Dimensional Materials
Published on: July 18, 2025
van der Waals Nanochemical Reactors
Zhaoyi Joy Zheng1,2, Haosen Guan1, Danrui Ni3
1Department of Physics, Princeton University, Princeton, New Jersey 08544, United States.
Van der Waals (vdW) stacks act as nanochemical reactors for synthesizing high-quality single crystals of quantum materials. This versatile method enables the growth of elemental and compound crystals for advanced electronic discoveries.
Area of Science:
- Materials Science
- Condensed Matter Physics
- Nanotechnology
Background:
- Synthesizing high-quality single crystals for quantum electronics is difficult for novel materials.
- Existing methods face limitations in scalability and material compatibility.
Purpose of the Study:
- To introduce and demonstrate the utility of van der Waals (vdW) stacks as nanochemical reactors for single-crystal synthesis.
- To explore the broad applicability of this method for growing diverse quantum materials.
Main Methods:
- Utilized vdW stacks as nanoreactors by encapsulating atomically thin reactants within inert vdW layers.
- Achieved nanoconfined synthesis, resulting in encapsulated single crystals.
- Synthesized elemental tellurium and palladium-tellurium (Pd-Te) compound crystals.
Main Results:
- Confirmed high crystalline quality of synthesized tellurium and Pd-Te single crystals via structural characterization.
- Observed the intrinsic semiconducting gap in tellurium crystals.
- Discovered superconductivity in nonstoichiometric PdTe1-x with reduced tellurium content.
Conclusions:
- vdW nanoreactors offer a generalizable, chip-integrable, and nanofabrication-compatible approach for single-crystal synthesis.
- This method expands the accessible landscape of quantum materials for electronic applications.
- The technique is suitable for various processing conditions and material types.
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