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Updated: Jan 29, 2026

Interfacial Molecular-level Structures of Polymers and Biomacromolecules Revealed via Sum Frequency Generation Vibrational Spectroscopy
Published on: August 13, 2019
Way More than the Sum of Their Parts: From Statistical to Structural Mixtures
1Complexity Sciences Center and Physics and Astronomy Department, University of California at Davis, One Shields Avenue, Davis, CA 95616, USA.
Abstract:
We show that mixtures comprising multicomponent systems typically are much more structurally complex than the sum of their parts; sometimes, infinitely more complex. We contrast this with the more familiar notion of statistical mixtures, demonstrating how statistical mixtures miss key aspects of emergent hierarchical organization. This leads us to identify a new kind of structural complexity inherent in multicomponent systems and to draw out broad consequences for system ergodicity.
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