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Multistep Relaxation Pathway from Glass to Crystal Development in Poly(l‑lactide)

Lorenzo Augusto Rocchi1, Elisa Sturabotti1, Andrea Martinelli1

  • 1Department of Chemistry, Sapienza University of Rome, P.le Aldo Moro 5, 00185 Rome, Italy.

Macromolecules
|March 2, 2026
PubMed
Summary

Researchers discovered a new transformation in amorphous poly-(l-lactide) (PLLA) within the supercooled liquid (SCL) phase before crystallization. This SCL transformation involves conformational changes, leading to a more stable PLLA state via a hierarchical relaxation pathway.

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