Oxygen vacancy-mediated interface coupling in Bi₂O₃/Bi@Bi₂MoO_6-x/TiO₂ double S-scheme heterojunction for efficient...

Indole, a recalcitrant nitrogen-containing heterocyclic compound in coal chemical wastewater, poses significant challenges to water resource recovery. Herein, a novel Bi₂O₃/Bi@Bi₂MoO_6-x/TiO₂ double S-scheme heterojunction with oxygen vacancy (OV)-mediated interfacial bonding was constructed via a solvothermal-alkaline treatment strategy. Systematic characterization revealed that oxygen vacancies (OVs) promote the formation of Mo-O(BO)-Bi and Mo-O(TO)-Ti interfacial bonds, which induce dual built-in electric fields and establish directional charge transfer pathways. This unique architecture facilitates efficient spatial separation of photogenerated carriers. Density functional theory (DFT) calculations demonstrate that OVs enhance interfacial bonding, generating dual electric fields that establish a high-potential dual S-scheme heterojunction. The rapid S-scheme electron transfer maintains a strong redox potential, synergizing with OVs to activate O₂, achieving 79.55% degradation and 64.96% mineralization of indole. Radical trapping experiments confirmed that ¹O₂ is the primary oxidant in this detoxification pathway. Gas chromatography-mass spectrometry (GC-MS) analysis and T.E.S.T. toxicity assessment revealed that intermediates become less toxic during indole photodegradation. This work provides a promising strategy for designing efficient heterojunction photocatalysts for the removal of refractory pollutants from wastewater.