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Updated: Apr 14, 2026

Synthesis of Nine-atom Deltahedral Zintl Ions of Germanium and their Functionalization with Organic Groups
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Published on: February 11, 2012

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Intermolecular Electrophilic Germylation Using GeCl4 and Al2Cl6.

Justyna Łosiewicz1, Milan Kumar Bisai1, Zachary A Bub1

  • 1EaStCHEM School of Chemistry, University of Edinburgh, Edinburgh, UK.

Angewandte Chemie (International Ed. in English)
|April 13, 2026
PubMed
Summary

Researchers developed the first effective intermolecular Germa-Friedel-Crafts reaction. This new method uses germanium tetrachloride and a pyridine base for efficient C-H germylation of arenes, enabling selective synthesis of aryl germanes.

Keywords:
C–H germylationLewis acidsaluminum trichlorideelectrophilic substitutiongermanium

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