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Updated: Jun 12, 2026

Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of Chalcogenidoplumbates(II or IV)
Published on: December 29, 2016
Chalcogen···π Bonding Catalysis: Concept, Reaction Development and Emerging Opportunities
Haofu Zhu1, Hang Zhou1, Yao Wang1
1School of Chemistry and Chemical Engineering, Shandong University, Jinan, P. R. China.
Abstract:
The activation of π-systems by noncovalent interactions has long been considered as an unfavorable approach. However, recent investigations on chalcogen···π (Ch···π) interactions have demonstrated that it is a reliable and powerful platform to catalyze diverse transformations involving various π-systems, even enabling the achievement of reactions that are otherwise unattainable by other approaches. To highlight this fast-moving frontier, this review summarizes this emerging topic and discusses catalyst design, mechanistic insights, and catalytic strategies based on pure and cooperative chalcogen···π interactions.
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