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Updated: Jun 12, 2026

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Atomically Precise Ag42 Nanocluster: Shell Structure Modulation and Photothermal Conversion Properties.

Along Ma1, Yonggang Ren2, Shuo Zhang1,2

  • 1State Key Laboratory of Advanced Optical Polymer and Manufacturing Technology, College of Chemistry and Molecular Engineering,Qingdao University of Science and Technology, Qingdao 266042,P. R. China.

Inorganic Chemistry
|June 10, 2026
PubMed
Summary

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This summary is machine-generated.

New silver nanoclusters (Ag42) with a hollow core and integrated shell show superior photothermal conversion and stability. This breakthrough offers insights for designing advanced photothermal materials.

Area of Science:

  • Nanomaterials Chemistry
  • Photothermal Conversion
  • Surface Science

Background:

  • Shell structure significantly impacts photothermal conversion properties of nanomaterials.
  • Developing efficient and stable photothermal agents is crucial for various applications.

Purpose of the Study:

  • To synthesize and characterize a novel silver nanocluster (Ag42) with a unique core-shell structure.
  • To evaluate the photothermal performance and stability of Ag42 compared to existing materials.
  • To elucidate the structure-property relationships governing the enhanced photothermal conversion.

Main Methods:

  • Synthesis and characterization of Ag42 nanoclusters.
  • Photothermal performance evaluation under 450 nm light irradiation.
  • Stability testing under prolonged irradiation.

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  • Analysis of photophysical properties (molar absorption coefficient, PLQY) and structural rigidity.
  • Main Results:

    • Ag42 nanoclusters demonstrated a remarkable temperature rise (22.4 °C) and photothermal conversion efficiency (75.27%).
    • Ag42 significantly outperformed the classical Ag44 nanoclusters in both efficiency and stability.
    • Enhanced performance is attributed to shell modulation, high molar absorption coefficient, favorable charge transfer, negligible PLQY, and increased shell rigidity.

    Conclusions:

    • The novel Ag42 nanoclusters exhibit superior photothermal conversion properties and stability.
    • Shell structure plays a critical role in modulating photothermal performance.
    • These findings pave the way for designing next-generation photothermal materials.