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Updated: Jun 17, 2026

Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production
Published on: December 6, 2021
CoFe alloy nanoparticles embedded in carbon nanofibers for efficient synthesis of ammonia from nitrate reduction
Haitao Yin1, Jingqi Huang1, Xiaoyu Liu1
1School of Materials and Energy, University of Electronic Science and Technology of China, Chengdu 611731, Sichuan, China. litingshuai@uestc.edu.cn.
Abstract:
Alloys can optimize the rate determining step of nitrate reduction through a synergistic effect, significantly reducing the reaction overpotential, so a series of CoxFey alloy nanoparticles embedded in carbon nanofibers (CNFs) are fabricated to reduce nitrate to ammonia. Co9Fe1@CNFs achieve a high ammonia yield rate of 31.1 mg h-1 mgcat..-1 and a high faradaic efficiency (FE) of 83.5% at -0.6 V vs. RHE. In situ electrochemical tests and density functional theory (DFT) calculations reveal that the reaction follows a deoxygenation-hydrogenation pathway, where the alloyed sites lower the rate-determining step (RDS) barrier to only 0.40 eV.
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