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NMR Spectrometers: Resolution and Error Correction01:14

NMR Spectrometers: Resolution and Error Correction

When magnetic nuclei in a sample achieve resonance and undergo relaxation, the signal detected in NMR is an approximately exponential free induction decay. Fourier transform of an exponential decay yields a Lorentzian peak in the frequency domain. Lorentzian peaks in an NMR spectrum are defined by their amplitude, full width at half maximum, and position, where the peak width is governed by the spin-spin relaxation time alone. In real experiments, however, the applied magnetic field is rendered...
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Related Experiment Video

Updated: Jun 18, 2026

Measurements of Long-range Electronic Correlations During Femtosecond Diffraction Experiments Performed on Nanocrystals of Buckminsterfullerene
08:44

Measurements of Long-range Electronic Correlations During Femtosecond Diffraction Experiments Performed on Nanocrystals of Buckminsterfullerene

Published on: August 22, 2017

Diffractive wavefront correction for Fe L-edge spectroscopy on the meV scale.

Christoph Braig1, Andrey Sokolov2, Frank Siewert2

  • 1Institute for Applied Photonics eV, Rudower Chaussee 29/31, 12489 Berlin, Germany.

Journal of Synchrotron Radiation
|June 16, 2026
PubMed
Summary
This summary is machine-generated.

We developed a new instrument for high-resolution soft X-ray spectroscopy, achieving 12-15 meV energy resolution using a novel reflection zone plate. This advancement benefits large-scale facilities like synchrotron radiation sources and free-electron lasers.

Keywords:
X-ray spectroscopydiffractive opticsreflection zone plateswavefront correction

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Published on: May 10, 2021

Area of Science:

  • Physics
  • Spectroscopy
  • Optics

Background:

  • High-resolution soft X-ray spectroscopy is crucial for materials science and physics.
  • Existing instruments face limitations in energy resolution and photon throughput.

Purpose of the Study:

  • To propose and simulate a novel wavelength-dispersive instrument for high-resolution soft X-ray spectroscopy.
  • To achieve an energy resolution of 12-15 meV at large-scale facilities.

Main Methods:

  • Utilizing a wavefront-corrected reflection zone plate (RZP) with a large aperture (40mm x 190mm) on a spherical Si substrate.
  • Employing a two-dimensional, adapted grating groove distribution to compensate for surface waviness.
  • Simulating performance at the Fe L-edge (700-730 eV).

Main Results:

  • Achieved an energy resolution of 12-15 meV in simulations.
  • Demonstrated precise control of tangential slope error (±0.1 arcsec) and deformation (±6.1 nm).
  • The RZP design collimates the diffracted beam to a 40mm focal line, minimizing photon loss and maximizing signal transmission.

Conclusions:

  • The proposed instrument enables unprecedented energy resolution in soft X-ray spectroscopy.
  • The RZP design offers high efficiency and broad signal acceptance, enhancing capabilities at synchrotron and free-electron laser facilities.