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Core-shell CuFeMnHCF@CuHCF: a high-rate and durable Prussian blue cathode for sodium-ion batteries
Shumin Sun1, Haibo Lei1, Yunpeng Ma1
1College of Material and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou, 450001, P. R. China. smsun@zzuli.edu.cn.
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A core-shell CuFeMnHCF@CuHCF composite was prepared via a continuous one-pot co-precipitation and ion exchange method. The monoclinic Cu-doped FeMnHCF core and the cubic Cu2Fe(CN)6 shell can mitigate Jahn-Teller distortion and suppress Mn dissolution. This synergy enables superior rate capability and 79.0% capacity retention after 400 cycles, with in situ XRD revealing a reversible monoclinic ↔ cubic transition.
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