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Updated: Jul 12, 2026

A Technical Guide for Performing Spectroscopic Measurements on Metal-Organic Frameworks

A Technical Guide for Performing Spectroscopic Measurements on Metal-Organic Frameworks

Published on: April 28, 2023

Gas Sorption Measurements in MOFsA Tutorial for Beginners.

Marzena Pander¹, Chiranjib Gogoi², Wojciech Bury²

¹Faculty of Chemistry, Jagiellonian University, Gronostajowa 2, 30-387 Kraków, Poland.

ACS Materials Au

|July 11, 2026

Summary

This tutorial guides new researchers on low-pressure gas adsorption measurements for porous materials like metal-organic frameworks (MOFs). It covers sample preparation, activation, measurement, and data analysis for characterizing textural properties.

Keywords:

BET analysis MOF adsorption data reporting isotherm metal−organic frameworks pore volume porosity sample activation tutorial

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Area of Science:

Materials Science
Physical Chemistry
Nanotechnology

Background:

Adsorption measurements are essential for characterizing porous solids, determining properties like Brunauer-Emmett-Teller (BET) surface area, pore volume, and pore size distribution.
Accurate gas sorption analysis in metal-organic frameworks (MOFs) is vital for assessing their performance and understanding their textural characteristics, including adsorption capacity.

Purpose of the Study:

To provide a practical guide for students and new researchers on performing low-pressure gas adsorption measurements (up to atmospheric pressure).
To detail key aspects of gas sorption analysis in metal-organic frameworks (MOFs), serving as an entry-level teaching resource.

Main Methods:

Detailed discussion of sample preparation techniques specific to porous materials.
Explanation of various activation strategies to ensure accurate adsorption measurements.
Overview of low-pressure gas adsorption measurement techniques and data analysis procedures.

Main Results:

The tutorial comprehensively covers sample preparation, activation, measurement techniques, and data analysis for gas sorption in MOFs.
It emphasizes the importance of these methods for accurate determination of textural properties and host-guest interactions.

Conclusions:

This tutorial serves as a foundational resource for understanding and conducting gas sorption measurements in metal-organic frameworks (MOFs).
It equips researchers with the necessary knowledge to characterize MOFs effectively using adsorption techniques.