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Updated: Aug 5, 2026

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
19:58

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions

Published on: July 30, 2017

Palladium-Catalyzed Cross-Coupling of Iodocarboranes with B2pin2

Xuan-Hao Cao1, Wen-Jin Zou1, Ke Cao1

  • 1State Key Laboratory of Environment-friendly Energy Materials & Inertial Confinement Fusion Energy Materials Key Laboratory of Sichuan Province & School of Materials and Chemistry, Southwest University of Science and Technology, Mianyang, Sichuan621010, P. R. China.

Inorganic Chemistry
|July 27, 2026
PubMed
Summary

This study introduces a new palladium-catalyzed method for borylating the B-I bond in carboranes using bis(pinacolato)diboron. This enables the synthesis of novel carborane derivatives, offering new pathways for carborane functionalization.

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