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Updated: Aug 5, 2026

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Synthesis of Programmable Main-chain Liquid-crystalline Elastomers Using a Two-stage Thiol-acrylate Reaction
Published on: January 19, 2016
Modular synthesis of chemically programmable superlattices
Jingyuan Zhou1,2, Huaying Ren3, Yu Huang1,4,5
1Department of Chemistry and Biochemistry, University of California Los Angeles, Los Angeles, CA, USA.
Nature Materials
|July 29, 2026
Summary
Researchers are developing new methods to synthesize functional intercalated superlattices. These advanced materials combine 2D atomic crystals with self-assembled interlayers for novel electronic and optical properties.
Area of Science:
- Materials Science
- Condensed Matter Physics
- Nanotechnology
Background:
- Two-dimensional atomic crystals (2DACs) possess van der Waals (vdW) gaps enabling intercalation.
- Intercalation allows self-assembly of ordered interlayers, forming superlattices with combined properties of 2DACs and functional interlayers.
Purpose of the Study:
- To review functional building blocks for intercalated superlattices.
- To examine challenges and strategies in synthesizing and assembling these functional materials.
- To establish principles for designing chemically programmable superlattices with tailored functionalities.
Main Methods:
- Classification of functional building blocks for superlattice construction.
- Analysis of current synthesis and assembly strategies.
- Identification of key challenges in incorporating reactive interlayers.
Main Results:
- Functional interlayers offer programmable electronic, optical, and magnetic properties.
- Intercalated superlattices integrate quantum and collective phenomena for advanced functionalities.
- Synthesis of functional superlattices is complex due to interlayer reactivity.
Conclusions:
- Emerging strategies are crucial for overcoming synthesis challenges.
- Modular design principles are needed for tailored superlattices.
- This review guides the development of next-generation functional materials.

