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Updated: Aug 22, 2026
Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of Phosphorus(I)
Published on: November 22, 2016
Preparation, structural characterization, and electrocatalytic oxygen evolution activity of the mixed metal phosphide
Chihiro Yoshikawa1, Mai Nakanishi1, Satoshi Muratsugu1
1Department of Chemistry, Graduate School of Science/Integrated Research Consortium on Chemical Sciences (IRCCS)/Research Center for Materials Science (RCMS), Nagoya University, Furo-cho, Chikusa-ku, Nagoya, Aichi 464-8602, Japan. muratsugu.satoshi.a5@f.mail.nagoya-u.ac.jp.
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PtRuP, a mixed metal phosphide with a CaF2-type structure featuring randomly distributed Pt and Ru atoms in tetrahedral sites, was synthesized and exhibited catalytic activity toward the electrochemical oxygen evolution reaction, whereas the corresponding single metal phosphides were essentially inactive over the same overpotential range.
