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Updated: Sep 9, 2026

Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of Phosphorus(I)
Published on: November 22, 2016
{2-[tert-But-yl(pyridin-2-yl)phosphino]phen-yl}diphenyl-phosphine
Joseph Görl1, Rauf Razzaq2, Anke Spannenberg2
1RWTH Aachen University, Institute of Technical and Macromolecular Chemistry, Worringerweg 2, 52074 Aachen, Germany.
Abstract:
The title compound, C27H27NP2, is a new potential asymmetric P,P,N ligand and consists of a di-phenyl-phosphino and a tert-but-yl(pyridin-2--yl)phosphino group bridged by a 1,2-phenyl-ene backbone. The dihedral angles between the central and pendant aromatic rings are 83.07 (6), 85.99 (5) and 82.80 (6)°. In the extended structure, weak C-H⋯π inter-actions link the mol-ecules.
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