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Synthesis of Information-bearing Peptoids and their Sequence-directed Dynamic Covalent Self-assembly
Published on: February 6, 2020
Synthesis and structure of benzyl 4-{[4-(hex-yloxy)benzo-yl]-oxy}benzoate
P Roopadevi1, H T Srinivasa2, H C Devarajegowda1
1Department of Physics Yuvaraja's College University of Mysore,Mysore-570005 Karnataka India.
Abstract:
In the title compound, C27H28O5, the aromatic ring of the 4-hexyl-oxybenzoyl moiety and the central benzoate ring are twisted relative to one another, subtending a dihedral angle of 39.7 (2)°. The pendant benzyl aromatic ring is nearly orthogonal to the central benzoate ring, forming a dihedral angle of 89.3 (2)°. The hex-yloxy chain adopts an extended, approximately all-anti conformation and two short intra-molecular C-H⋯O contacts are observed. In the extended structure, C-H⋯π inter-actions help to consolidate the packing. Hirshfeld surface analysis and the corresponding two-dimensional fingerprint plots indicate that H⋯H contacts constitute the largest contribution to the crystal surface, accounting for 55.4%, followed by C⋯H/H⋯C contacts (22.9%) and O⋯H/H⋯O contacts (16.3%).
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