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Updated: Sep 9, 2026
Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
Published on: February 15, 2016
Crystal structure and Hirshfeld surface analysis of
Farid N Naghiyev1, Victor N Khrustalev2,3, Elena Yu Nevskaya2
1Faculty of Chemistry, Baku State University, Z. Khalilov str. 23, Az, 1148, Baku, Azerbaijan.
Abstract:
The title mol-ecule, C23H18ClNO2S·H2O, has a stable conformation with S(5) and S(6) rings formed by intra-molecular C-H⋯S and C-H⋯O hydrogen bonds. The water mol-ecule and the carboxyl oxygen atom of the main mol-ecule also make an O-H⋯O hydrogen bond. In the crystal, N-H⋯O, O-H⋯Cl, O-H⋯O and C-H⋯O hydrogen bonds connect mol-ecules to form a three-dimensional network. The mol-ecules are further connected by C-H⋯π inter-actions and face-to-face π-π inter-actions into layers parallel to the (001) plane.
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