Twist-Tunable Interlayer Excitons in Anisotropic ReS2/ReSe2 Heterostructures
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Updated: Nov 5, 2026

Fabricating van der Waals Heterostructures with Precise Rotational Alignment
Published on: July 5, 2019
Krishna P Dhakal1, Sean F Peterson2, Daekwon Lee3
1Department of Energy Science, Sungkyunkwan University, Suwon16419, Republic of Korea.
Abstract:
Interlayer excitons (IEs) in van der Waals heterostructures offer tunable excitonic states with long lifetimes and permanent dipole moments. Prior studies focused on isotropic 2H-phase transition metal dichalcogenides, where bright IE emission is confined near high-symmetry twist angles (0° and 60°), restricting tunability. Here, heterobilayers of monolayer ReS2 and ReSe2, both in the 1T' phase, exhibit robust polarized IE emission near 1.2 eV across the full twist-angle range (1°-88°), reflecting a hybridization landscape governed by lattice anisotropy rather than valley alignment. The lowest-energy IE transition exhibits a nonmonotonic twist-angle dependence with a total modulation range of ∼60 meV, consistent with moiré-driven band renormalization and modulation of interlayer coupling revealed by first-principles calculations and low-frequency Raman spectroscopy, respectively. Overall IE energy tunability extends to ∼100 meV with multilayer ReS2 and excitation energy variation. These results establish ReS2/ReSe2 as a versatile infrared IE platform enabling polarization-resolved emitters and detectors beyond 2H-symmetry constraints.
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