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Synthesis and activity of dipeptides containing epsilon-aminocaproic acid

K Midura-Nowaczek1, I Bruzgo, W Roszkowska-Jakimiec

  • 1Institute of Chemistry, Warsaw University, Bialystok, Poland.

Acta Poloniae Pharmaceutica
|January 1, 1994
PubMed

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Preparation of Amides01:29

Preparation of Amides

Amides are synthesized by treating carboxylic acids with amines in the presence of dehydrating agents like dicyclohexylcarbodiimide (DCC).
The DCC-promoted synthesis of amides begins with the protonation of DCC by carboxylic acid. The protonation makes it a better acceptor. Next, the addition of carboxylate to the protonated carbodiimide gives a reactive acylating agent.
Subsequently, the amine acts as a nucleophile that attacks the acylating agent to form a tetrahedral intermediate. In the...