Gonzalo Otero1, Giulio Biddau, Carlos Sánchez-Sánchez

  • 1Instituto de Ciencia de Materiales de Madrid (CSIC), Cantoblanco, 28049 Madrid, Spain.

Nature
|August 16, 2008
PubMed
まとめ

研究者は,芳香的前駆体からフルレレンとトリアザフルレンを合成するための新しい表面触媒方法を開発しました. この非常に効率的なプロセスは,ほぼ100%の収穫を達成し,新しいフルレン構造への制御された経路を提供します.

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Alkenes undergo reduction by the addition of molecular hydrogen to give alkanes. Because the process generally occurs in the presence of a transition-metal catalyst, the reaction is called catalytic hydrogenation.
Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
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Reduction of Alkenes: Asymmetric Catalytic Hydrogenation

Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
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Introduction
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