高ポリマー含有量で効率的なポリマー太陽電池に向けた分子設計
Deping Qian1, Wei Ma, Zhaojun Li
1State Key Laboratory of Polymer Physics and Chemistry, Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China.
Journal of the American Chemical Society
|May 28, 2013
まとめ
研究者らは,効率的なポリマー太陽電池 (PSC) のための新しいポリマーであるPBT1を開発しました. この進歩は,非常に薄いフィルムでも高い性能を実現し,6.88%のパワー変換効率を達成します.
科学分野:
- マテリアルサイエンス 材料科学
- オーガニック・エレクトロニクス
- フォトボルトイカは,太陽光発電です.
背景:
- ポリマー太陽電池 (PSC) は,柔軟性と低製造コストにより,従来のシリコンベースの太陽光発電の有望な代替品です.
- ドナーポリマーの分子構造の最適化は,PSCにおける光吸収と電荷輸送特性の強化に不可欠です.
- 超薄型PSCアクティブ層で高電力変換効率 (PCE) を達成することは,依然として大きな課題です.
研究 の 目的:
- ポリマー太陽電池に適用するための新しいポリチオフェン誘導体PBT1の設計と合成.
- 改善された光伏性能のためのPBT1の構造-特性関係を調査する.
- 非常に薄いPSCフィルムで効率的な光吸収を達成する分子設計の有効性を実証する.
主な方法:
- 新型ポリチオフェン誘導体PBT1.1の合成
- PBT1を活性層材料として利用したポリマー太陽電池 (PSC) の製造.
- 電力変換効率 (PCE) の測定を含む,光伏の性能の特徴付け.
主要な成果:
- PBT1ポリチオフェン誘導体の成功設計と合成.
- PBT1の超薄膜 (75nm活性層) で効率的な光吸収能力を実証.
- 75nmアクティブ層のPSC装置で6.88%のパワー変換効率を達成しました.
結論:
- PBT1は,高性能ポリマー太陽電池の新鮮で効果的な素材です.
- 分子構造工学は,薄膜PSCの光伏性能を最適化するための実行可能な戦略です.
- この結果は,効率的かつ費用対効果の高い有機光伏装置の開発におけるPBT1の可能性を強調しています.
関連する概念動画
Molecular Weight of Step-Growth Polymers
Step growth polymerization involves bi or multifunctional monomers. Bifunctional monomers react to form linear step growth polymers, whereas multifunctional monomers react to form non-linear or branched polymers.
As the step-growth polymerization involves step-wise condensation of monomers, the molecular weight also builds up eventually. Consequently, high molecular weight polymers are obtained at the late stages of the polymerization, where 99% of monomers have been consumed.
The extent of the...
As the step-growth polymerization involves step-wise condensation of monomers, the molecular weight also builds up eventually. Consequently, high molecular weight polymers are obtained at the late stages of the polymerization, where 99% of monomers have been consumed.
The extent of the...
Polymers: Molecular Weight Distribution
For any given polymer, the weight average molecular weight (Mw) is higher than, if not equal to, the number average molecular weight (Mn). The only situation in which the weight average molecular weight and the number average molecular weight are equal is when a polymer consists only of chains with equal molecular weight. However, this never happens in a synthetic polymer, since it is difficult to control the polymerization process up to a molecular level with accuracy to a hundred percent.
Polymers
The word polymer is derived from the Greek words “poly” which means “many” and “mer” which means “parts”. Polymers are long chains of molecules composed of repeating units of smaller molecules, known as monomers. They either occur naturally, such as DNA and proteins, or can be constructed synthetically, like plastics. They have varied structural characteristics, such as linear chains, branched chains, or complex networks, that contribute to the properties that they exhibit. Additionally,...


