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Updated: Dec 24, 2025

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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磁気的に堅固な三重基状硫黄と炭化水素のダイラジカル・ディケーション

Shuxuan Tang1, Li Zhang2, Huapeng Ruan1

  • 1State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210023, China.

Journal of the American Chemical Society
|April 10, 2020
PubMed
まとめ

研究者らは,テトラチオレートピレンの誘導体から安定した根性カチオンと二根性カチオン塩を合成した. ダイラジカル・ディケーションは三重基底状態を示し,高スピン硫黄-炭化水素ダイラジカル化学の重要な進歩を示している.

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