基于超氧化的氧电池
Jun Lu1, Yun Jung Lee2, Xiangyi Luo3,4
1Chemical Sciences and Engineering Division, Argonne National Laboratory, Argonne, Illinois 60439, USA.
Nature
|January 12, 2016
概括
研究人员使用石墨烯阴极在氧电池中稳定了纯超氧化物 (LiO2). 这一突破使得高能量密度电池和潜在的氧气储存应用成为可能.
科学领域:
- 材料科学
- 电化学
- 能量储存
背景情况:
- 氧 (Li-O2) 电池具有很高的能量密度.
- 之前的研究已经努力合成纯超氧化物 (LiO2),因为它的不稳定性.
- 2在热力学上不稳定,不成比例地变成过氧化 (Li2O2).
研究的目的:
- 用于稳定晶体超氧化物 (LiO2),用于Li-O2电池.
- 调查纯LiO2形成的可能性及其电化学特性.
- 探索高能量密度电池开发的新途径.
主要方法:
- 使用基于石墨烯的阴极稳定LiO2在一个Li-O2电池.
- 在阴极表面使用纳米粒子来促进模板生长机制.
- 应用各种特征技术来确认LiO2的存在和缺乏Li2O2.
主要成果:
- 在一个Li-O2电池中成功合成和稳定晶体LiO2.
- 鉴定证实没有过氧化 (Li2O2).
- 基于LiO2的电池表现出稳定的循环,充电电位约为3.2V.
结论:
- 开发的基于石墨烯的阴极有效地稳定了LiO2,克服了以前的合成挑战.
- 这种稳定可以在高能量密度电池中合成和利用LiO2.
- 这些发现表明LiO2在电池之外的潜在应用,例如储存氧气.
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