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Updated: Jul 4, 2026
Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
Published on: February 15, 2016
Crystal engineering in the gem-alkynol family: interplay between strong and weak interactions in structures of
Abstract:
Structures of the title compounds are all mediated by strong cooperative arrangements of O-H.O hydrogen bonds, supported by a variety of weaker interactions which affect the type of O-H.O synthon that is formed. The tetrafluoro compound contains hexameric O-H.O synthons in a supramolecular chair conformation, together with C identical withC-H.F interactions. However, the tetrachloro and tetrabromo compounds both form tetrameric O-H.O synthons. This dominant pattern is supported by halogen.halogen interactions having one C-Cl[Br].Cl[Br] angle close to 180 degrees and the other close to 90 degrees, and by C identical withC-H.Cl[Br] interactions.
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