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Studies in 3-oxy-assisted 3-aza cope rearrangements
Mário J S Gomes1, Lalit Sharma, Sundaresan Prabhakar
1Secção de Química Orgânica Aplicada, Departamento de Química, CQFB-REQUIMTE, and SINTOR-UNINOVA, campus FCT-UNL, Quinta da Torre, 2829 Monte de Caparica, Portugal.
Chemical Communications (Cambridge, England)
|July 18, 2002
Abstract:
On thermolysis appropriately substituted N-silyloxy-N-allyl enamines undergo smooth 3,3-sigmatropic rearrangments to the corresponding N-silyloxy imino ethers.