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Monomeric uni-ligated aluminates
M J Harvey1, M Proffitt, P Wei
1Department of Chemistry, University of Kentucky, Lexington, KY 40506-0055, USA.
Chemical Communications (Cambridge, England)
|September 21, 2002
Abstract:
The tetradentate ligand, common name Salban(But)H4 (N,N'-bis(2-hydroxy-3,5-di-tert-butylbenzyl)-1,4-diaminobutane) combines with appropriate amounts of LiAlH4 to produce the unique monomeric, uni-ligated aluminate [Salban(But)Al]Li(thf)2 (1) and the bimetallic derivative Salban(But)(AlH2Li(thf)2)2 (2).