Related Experiment Videos
C-phosphanyl-C-chloroiminium salts as electrophilic carbene synthetic equivalents
Nathalie Merceron1, Antoine Baceiredo, Heinz Gornitzka
1Laboratoire Hétérochimie Fondamentale et Appliquée du CNRS (UMR 5069), Université Paul Sabatier, 118, route de Narbonne, 31062 Toulouse, France.
Chemical Communications (Cambridge, England)
|October 26, 2002
Abstract:
C-Phosphanyl-C-chloroiminium salts formally react as phosphonio(amino)carbenes with tert-butyl isocyanide and trimethylphosphine, and as R2NC+ with vinyl ether and diisopropylamine.