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Variable coordination chemistry of the phospha(III)guanidinate anion; application as a metal-functionalised phosphine
Martyn P Coles1, Peter B Hitchcock
1Chemical Laboratories, University of Sussex, Falmer, Brighton, UK BN1 9QJ. m.p.coles@sussex.ac.uk
Chemical Communications (Cambridge, England)
|December 14, 2002
Abstract:
Structural investigation of Li-complexes of the phospha(III)guanidinate anion [Ph2PC[NiPr]2]- revealed variable coordination to lithium; synthesis of the dimethyl aluminium compound, (Ph2PC[NiPr]2)AlMe2, which behaves as a metal-functionalised phosphine ligand towards platinum, is reported.