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Cyclopentadienyl benzamidinato chromium complexes as models for alkyl halide activation by chromium reagents
Amanda J Gallant1, Kevin M Smith, Brian O Patrick
1Department of Chemistry, University of Prince Edward Island, 550 University Avenue, Charlottetown, PE, Canada C1A 4P3.
Chemical Communications (Cambridge, England)
|December 14, 2002
Abstract:
Cyclopentadienyl complexes of Cr(II) and Cr(III) are stabilized by bis(trimethylsilyl)benzamidinato ligands, allowing the resulting well-defined compounds to serve as models for alkyl halide activation by mid-valent Cr-based reagents.