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Preparation of N-(2-alkoxyvinyl)sulfonamides from N-tosyl-1,2,3-triazoles and Subsequent Conversion to Substituted Phthalans and Phenethylamines
Published on: January 3, 2018
Investigation of the early stages in soraphen A biosynthesis
Alison M Hill1, Betty L Thompson, Jonathan P Harris
1Department of Chemistry, King's College London, Strand, London, UK WC2R 2LS. a.m.hill@ex.ac.uk
Chemical Communications (Cambridge, England)
|July 5, 2003
Abstract:
The unusual benzoate starter unit in soraphen A derives from phenylalanine via cinnamate in a beta-oxidative (plant-like) pathway; 3-phenyl-3-hydroxypropanoate incorporates directly into soraphen by loading onto module 2 of the PKS and indirectly from the beta-oxidative pathway to generate benzoyl CoA.
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