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Updated: Aug 30, 2026

On the Preparation and Testing of Fuel Cell Catalysts Using the Thin Film Rotating Disk Electrode Method
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Extended X-ray absorption fine structure (EXAFS) characterisation of dilute palladium homogeneous catalysts
Steven G Fiddy1, John Evans, Mark A Newton
1Department of Chemistry, The University of Southampton, Highfield, Southampton, UK SO17 1BJ. fiddy@esrf.fr
Abstract:
Highly dilute EXAFS characterisation for the elucidation of species involved in Heck chemistry is demonstrated; the major "monomer" species of Herrmann's acetate-bridged phosphapalladadacycle is characterised and species present during the course of a 50 ppm [Pd] Pd(OAc)2/PBu(t)3 catalysed Heck reaction are presented.
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