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Inclusion of C60 into an adjustable porphyrin dimer generated by dynamic disulfide chemistry

Amy L Kieran1, Sofia I Pascu, Thibaut Jarrosson

  • 1Department of Chemistry, University of Cambridge, Lensfield Rd, Cambridge, UK CB2 1EW.

Chemical Communications (Cambridge, England)
|March 3, 2005
PubMed

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Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.