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Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction
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Published on: April 10, 2018

Sulfoxide carbon-sulfur bond activation

Joseph M O'Connor1, Kevin D Bunker, Arnold L Rheingold

  • 1Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, California 92093, USA. jmoconnor@ucsd.edu

Journal of the American Chemical Society
|March 24, 2005
PubMed
Summary

Organometallic chemistry research reveals new cobalt complexes. Alkynylsulfoxide reacts with cobalt to form cobaltosulfoxide, which oxidizes to a cobaltosulfone or converts to cobalt-thiolato dimers.

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