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Surface charge controlled magnetic nanoparticles with grafting of poly(4-vinylpyridine)
Makoto Takafuji1, Takamasa Mimaki, Zhenghe Xu
1Department of Applied Chemistry and Biochemistry, Faculty of Engineering, Kumamoto University, 2-39-1 Kurokami, Kumamoto, Japan.
Abstract:
Poly(4-vinylpyridine)-grafted magnetic nanoparticles were prepared by the "graft to" method. Surface-modified magnetic particles are covered with a hydrophobic layer because it can be dispersed in organic solvents such as methanol, toluene, benzene, and chloroform, but not in water. Surface charge control with magnetic nanoparticles of various isoelectric point was achieved by quaternization of pyridyl groups, and the positively charged particles can be dispersed in water within a wide range of pH.

