Validity of NMR pore-size analysis of cultural heritage ancient building materials containing magnetic impurities

NMR relaxation time distributions, obtained with laboratory and portable devices, are utilized to characterize the pore-size distributions of building materials coming from the Roman remains of the Greek-Roman Theatre of Taormina. To validate the interpretation of relaxation data in terms of pore-size distribution, comparison of results from standard and in situ NMR experiments with results of the mercury intrusion porosimetry (MIP) has been made. Although the pore-size distributions can be obtained by NMR in terms of either longitudinal (T(1)) or transverse (T(2)) relaxation times distributions, the shorter duration of the T(2) measurement makes it, in principle, preferable, although the determination of T(2) distributions is not necessarily an easy alternative to finding T(1) distributions. Among other things, the T(1) distribution is almost independent of the inhomogeneity of the magnetic field, while the T(2) distribution is strongly influenced by it. This paper was aimed at answering two questions: what are the validity limits to interpret NMR data in terms of pore-size distributions and whether the portable device can successfully be applied as a non-destructive and non-invasive tool for in situ NMR analysis of building materials, particularly those of Cultural Heritage interest.