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Pi-dimer formation as the driving force for calix[4]arene-based molecular actuators

Changsik Song1, Timothy M Swager

  • 1Department of Chemistry and Institute for Soldier Nanotechnologies, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA.

Organic Letters
|July 12, 2008
PubMed
Summary

Stable pi-dimers form from calix[4]arene molecular actuators during oxidation in dichloromethane. This pi-dimer formation is confirmed by UV-vis, EPR, and DPV, and depends on the calixarene hinge flexibility.

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