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Related Concept Videos

¹H NMR: Long-Range Coupling01:27

¹H NMR: Long-Range Coupling

The coupling interactions of nuclei across four or more bonds are usually weak, with J values less than 1 Hz. While these are usually not observed in spectra, the presence of multiple bonds along the coupling pathway can result in observable long-range coupling.
In alkenes, spin information is communicated via σ–π overlap, as seen in allylic (four-bond) and homoallylic (five-bond) couplings. These coupling interactions are stronger when the σ bond is parallel to the alkene π orbitals.
Directionality of Nuclear Transport01:42

Directionality of Nuclear Transport

Ras-related nuclear protein or Ran is a small G protein that cycles between its GTP and GDP bound states. Ran specific regulators, a Ran GTPase Activating Protein or RanGAP present in the cytosol and a Ran guanine nucleotide exchange factor or RanGEF present inside the nucleus regulate GTP/GDP exchange. A high concentration of GTP inside the cells, in addition to this asymmetric distribution of  Ran-specific regulators, leads to a higher RanGTP concentration inside the nucleus. This...
Spin–Spin Coupling: Two-Bond Coupling (Geminal Coupling)01:20

Spin–Spin Coupling: Two-Bond Coupling (Geminal Coupling)

Two NMR-active nuclei bonded to a central atom can be involved in geminal or two-bond coupling. Geminal coupling is commonly seen between diastereotopic protons in chiral molecules and unsymmetrical alkenes, among others.
The central atom need not be NMR-active because its electrons are affected by the electron polarization of the spin-active atoms. However, spin information is transmitted less effectively than in one-bond coupling, and 2J values are usually weaker than 1J values. The energy of...
NMR Spectroscopy: Spin–Spin Coupling01:08

NMR Spectroscopy: Spin–Spin Coupling

The spin state of an NMR-active nucleus can have a slight effect on its immediate electronic environment. This effect propagates through the intervening bonds and affects the electronic environments of NMR-active nuclei up to three bonds away; occasionally, even farther. This phenomenon is called spin–spin coupling or J-coupling. Coupling interactions are mutual and result in small changes in the absorption frequencies of both nuclei involved. While nuclei of the same element are involved in...
Spin–Spin Coupling: Three-Bond Coupling (Vicinal Coupling)01:22

Spin–Spin Coupling: Three-Bond Coupling (Vicinal Coupling)

Vicinal or three-bond coupling is commonly observed between protons attached to adjacent carbons. Here, nuclear spin information is primarily transferred via electron spin interactions between adjacent C‑H bond orbitals. This generally favors the antiparallel arrangement of spins, so 3J values are usually positive.
The extent of coupling depends on the C‑C bond length, the two H‑C‑C angles, any electron-withdrawing substituents, and the dihedral angle between the involved orbitals. The...
Propagation Speed of Electromagnetic Waves01:30

Propagation Speed of Electromagnetic Waves

Electromagnetic waves are consistent with Ampere's law. Assuming there is no conduction current Ampere's law is given as:

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Generation and Coherent Control of Pulsed Quantum Frequency Combs
06:42

Generation and Coherent Control of Pulsed Quantum Frequency Combs

Published on: June 8, 2018

Directional coupling for quantum computing and communication.

Georgios M Nikolopoulos1

  • 1Institute of Electronic Structure and Laser, FORTH, P.O. Box 1527, Heraklion 711 10, Crete, Greece.

Physical Review Letters
|December 31, 2008
PubMed
Summary
This summary is machine-generated.

We introduce directional coupling for selective state transfer between quantum wires. This concept is analyzed using a mathematical analogy to composite spin systems for quantum technologies.

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Area of Science:

  • Quantum physics
  • Quantum information science

Background:

  • Quantum computing and communication rely on controlled state transfer.
  • Efficient methods for state transfer are crucial for scalability.

Purpose of the Study:

  • To introduce and analyze the concept of directional coupling.
  • To explore selective state transfer between adjacent quantum wires.
  • To establish a mathematical framework for directional couplers.

Main Methods:

  • Developing a mathematical analogy between dual-channel directional couplers and composite spin systems.
  • Analyzing the properties of state transfer using this analogy.

Main Results:

  • Demonstrated the feasibility of directional coupling for selective state transfer.
  • Established a theoretical framework based on spin system analogies.
  • Provided a new perspective on quantum state manipulation.

Conclusions:

  • Directional coupling offers a promising mechanism for quantum information processing.
  • The spin system analogy simplifies the analysis of complex quantum coupling phenomena.
  • This work contributes to the development of advanced quantum communication and computing architectures.