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Updated: Jun 26, 2026

Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
Published on: September 18, 2016
Planar packing of tetrachlorodicyanobenzenes. II
1Department of Chemistry, University of Minnesota, Minneapolis, MN 55455-0431, USA. britton@umn.edu
Abstract:
Equimolar mixtures of ortho- and meta-, or ortho- and para-, or meta- and para-tetrachlorodicyanobenzene, C(6)Cl(4)(CN)(2), form structures with disordered layers containing both kinds of molecules in rhombohedral or pseudo-rhombohedral cells. These structures are similar to the structure of the rhombohedral form of the meta isomer. The guiding force appears to be an intermolecular synthon, in which a nitrile group in one molecule interacts with Cl atoms in two adjacent molecules with N...Cl distances of approximately 3.1 A.
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