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Updated: Jun 22, 2026

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
Published on: March 24, 2018
A three-dimensional adamantane-like nanoscopic cage built from four iodide-bridged triangular Mo3S7 cluster units
Larry R Falvello1, Rosa Llusar, Sonia Triguero
1Departamento de Química Inorgánica and I.C.M.A, Universidad de Zaragoza-C.S.I.C, Spain.
Abstract:
Chemical oxidation of a Mo(3)S(7) cluster featuring catecholate ligands, namely [Mo(3)S(7)(Cl(4)cat)(3)](2-) (Cl(4)cat = tetrachlorocatecholate), allows the isolation of a unique nanoscopic molecular cage made of four iodide-bridged Mo(3)S(7) clusters as the kinetically favoured product.
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