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Updated: Jun 21, 2026

Synthesis of Nine-atom Deltahedral Zintl Ions of Germanium and their Functionalization with Organic Groups
Published on: February 11, 2012
Formation and structures of germanium(II) Aryloxo/oxo clusters
Rebecca A Green1, Curtis Moore, Arnold L Rheingold
1Department of Chemistry, Oklahoma State University, Stillwater, Oklahoma 74078, USA.
Abstract:
The reaction of Ge[N(SiMe(3))(2)](2) with a phenol lacking a substituent in one ortho position results in the formation of polynuclear clusters having terminal aryloxide ligands and bridging O atoms. Structures of this type have not been observed for germanium(II) aryloxides before, and the source of the bridging O atoms in these clusters was determined to be the phenol reactant.
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